MATERIAL SAFETY DATA SHEET 1. PRODUCT & COMPANY IDENTIFICATION .. PRODUCT NAME ARTLINE® 470 INK (Invisible Ink) SKU # 25031 25041 y NAME OF SUPPLIER: Shachihata Inc. (U.S.A.) y NAME OF DEPARTMENT: Product Development Department y 24 HOUR EMERGENCY CONTACT: (800) 424-9300 y U.S.A. ADDRESS & TEL #: 3305 Kashiwa Street Torrance, CA 90505 USA (310) 530-4445 During business hours (310) 530-2892 (fax) HEALTH: 1 CODE: 0=MINIMAL FLAMMABILITY: 3 1=SLIGHT REACTIVITY: 0 2=MODERATE PERSONAL PROTECTION: A 3=SERIOUS 4=SEVERE SECTION 2: HAZARDOUS INGREDIENTS INGREDIENT PERCENT ACGIH-TLV OSHA-PEL CAS NO Isopropyl AlcoholEthyl Alcohol 50.00 50.00 400 PPM 1000 PPM 400 PPM 1000 PPM 67-63-0 64-17-5 SECTION 3: PHYSICAL & CHEMICAL CHARACTERISTICS Boiling Point: 176.5 F Melting Point: -128 F Vapor Density: 1.85 Specific Gravity: 0.785 Reactivity in Water: None Solubility in Water: Complete Auto Ignition: 545 F Vapor Pressure: 33 mm hg Appearance & Odor: Bluish Liquid, Alcohol Odor Appearance & Odor: VOC: 52.61 GMS/L LEL/UEL %: 2.0 19.0 Flash Point: 56 F Method: Closed Cup SECTION 4: FIRE & EXPLOSION DATA Extinguishing Media: Carbon Dioxide Extinguishing Media: Dry Chemical Extinguishing Media: Alcohol Foam Extinguishing Media: Universal Foam Extinguishing Media: Waterspray Special Fire Procedures: Wear self-contained breathing apparatus Prepared by: Product Development Department – Artline 470 Ink 1 of 3 Orig. Date: 02/06/01 Rev. Date: 01/24/03 Special Fire Procedures: Wear protective clothing and equipment Special Fire Procedures: Use waterspray to cool fire-exposed area Special Fire Procedures: Use waterspray to protect personnel Unusual Hazards: Wear face shield to protect face and eyes from contact with liquid or vapor. SECTION 5: REACTIVITY DATA Stable, Y=Yes, N=No: Y Conditions to Avoid: Heat, sparks and open flame Incompatibility: Ignition Sources Hazardous Decomposition: Burning will produce CO2 and probably CO Hazardous Polymerization: Will not occur Conditions to Avoid: None SECTION 6: HEALTH HAZARDS Acute: Dizziness; Eye irritation Chronic: Nausea from inhalation Chronic: Irritation of Mucous Membranes Signs & Symptoms of Exposure: Irritation to eyes Signs & Symptoms of Exposure: Dizziness from inhalation Signs & Symptoms of Exposure: Nausea and vomiting from ingestion Signs & Symptoms of Exposure: Coughing, Shortness of breath Medical Conditions aggravated: Irritation of mucosal membranes Medical Conditions aggravated: May worsen a cough Medical Conditions aggravated: Redness and swelling of eyes Medical Conditions aggravated: May worsen a headache Is chemical listed as carcinogen or potential carcinogen? National Toxicololgy Program, Y=Yes, N=No: N IARC Monographics, Y=Yes, N=No: N OSHA, Y=Yes, N=No: N First Aid for Inhalation: Remove to fresh air if overcome by vapor First Aid for Eyes: Flush with clean water for 15 minutes First Aid for Skin: Wash with water after prolonged contact. First Aid for Ingestion: Give pint of lukewarm water First Aid for Ingestion: Induce vomiting; get medical attention Routes of entry for inhalation: Avoid prolonged breathing of vapors Routes of entry for eyes: Avoid all contact with the eyes Routes of entry for skin: Avoid prolonged contact in liquid ink Routes of entry for ingestion: Do not take internally SECTION 7: SPECIAL PRECAUTIONS & SPILL/LEAK PROCEDURES Handling & Storage: Keep container closed when not in use Handling & Storage: Keep away from heat, sparks and open flame Handling & Storage: Avoid prolonged breathing of vapors Handling & Storage: Do not take internally Steps If Spilled: Eliminate sources of ignition; ventilate Steps if spilled: Contain & cover spill with an absorbent Steps If Spilled: Collect & dispose in chemical waste drum Steps if spilled: Do not allow spill to enter watercourses Waste Disposal: Incinerate in chemical furnace Waste Disposal: Must conform to local, state & federal regulations Prepared by: Product Development Department – Artline 470 Ink 2 of 3 Orig. Date: 02/06/01 Rev. Date: 01/24/03 SECTION 8: SPECIAL PROTECTION INFORMATION Respiratory Protection: General room ventilation is adequate Ventilation: Should be equal to outdoors Local Exhaust: N/A Mechanical: N/A Special: None Protective Gloves: Not necessary Eye Protection: Splash glasses Other Protection: Eye Bath Work/Hygienic Practices: Due care should be taken when using this product. SPECIAL MESSAGE SECTION: The hazards listed on this MSDS are taken from the MSDS for each of the ingredients in this mixture. In most cases, the maximum form of hazard is represented here. The TLV’s represent the conditions under which it is believed that nearly all workers may be repeatedly exposed day after day without adverse effect. It must be remembered that each individual reacts differently and some may experience discomfort while others do not. This MSDS is presented so that each individual will have the information to deal safely with the use of this product. All materials TSCA listed. DISCLAIMER SECTION: Disclaimer of Liability: As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim all liability for any use of this material. Information contained herein is given in good faith and believed to be true and accurate. But all statements or suggestions are made without any warranty, expressed or implied, regarding the accuracy of the information, the hazards connected with the use of the material or results to be obtained from the use thereof. Information on MSDS supplied by ink mfg. Prepared by: Product Development Department – Artline 470 Ink 3 of 3 Orig. Date: 02/06/01 Rev. Date: 01/24/03